A long wavelength (6 to 20 .mu.m) phototransistor is described which has n-doped silicon as emitter and collector regions bracketing a base region having a quantum well structure made up of alternating layers of p-doped silicon germanium and undoped silicon, The silicon germanium layer adjacent to the emitter region is thicker and has a higher percentage of germanium in order to provide a quantum well that is wider and deeper than the other quantum wells in the base region thereby resulting in a larger current and optical gain. The silicon barrier layer of the quantum well closest to the collector region is p-doped in order to reduce the leakage current of the base-collector junction.