发明授权
- 专利标题: Olefin polymerization catalyst and olefin polymerization process
- 专利标题(中): 烯烃聚合催化剂和烯烃聚合方法
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申请号: US100174申请日: 1993-08-02
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公开(公告)号: US5407882A公开(公告)日: 1995-04-18
- 发明人: Satoru Yamada , Akihiro Yano
- 申请人: Satoru Yamada , Akihiro Yano
- 申请人地址: JPX Shinnanyo
- 专利权人: Tosoh Corporation
- 当前专利权人: Tosoh Corporation
- 当前专利权人地址: JPX Shinnanyo
- 优先权: JPX4-226497 19920804; JPX4-235116 19920812; JPX4-326673 19921207
- 主分类号: C08F4/646
- IPC分类号: C08F4/646 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; B01J31/14
摘要:
A catalyst for polymerization of olefin is provided which comprises (A) a metallocene compound, (B) an organoaluminum compound, and (C) a metal borate or a metal aluminate. The metallocene compound (A) is represented by the general formula (1) below: ##STR1## where Cp.sup.1 and Cp.sup.2 are cyclopentadienyl group; R.sup.1 is an alkylene, arylalkylene, dialkylsilylene, dialkylgermanylene, alkylphosphinediyl, or alkylimino group, R.sup.1 crosslinking Cp.sup.1 and Cp.sup.2 together; m is 0 or 1; M is titanium, zirconium, or hafnium; and R.sup.2 and R.sup.3 are independently hydrogen, halogen, or a hydrocarbon group, an alkoxy group, or an aryloxy group having 1 to 12 carbons, the organic aluminum compound (B) is represented by the general formula (2) below:AlR.sup.4.sub.3 (2)where each R.sup.4 is independently hydrogen, alkyl, alkoxy, or an aryl group, at least one R.sup.4 being an alkyl group, and the metal borate or the metal aluminate (C) being represented by the general formula (3):(C(L).sub.n).sub.b (A).sub.d (3)where C is an alkali metal cation or an alkaline earth metal cation; L is a Lewis base; A is an art ion having elemental boron or elemental aluminum; n is an integer of from 0 to 6; b and d are respectively an integer selected to balance the electric charge.
公开/授权文献
- USD429097S Handles in a pair of swinging doors 公开/授权日:2000-08-08
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