Invention Grant
US5451646A Technique for reducing the molecular weight and improving the
processability of cis-1,4-polybutadiene
失效
降低分子量和提高顺式-1,4-聚丁二烯加工性能的技术
- Patent Title: Technique for reducing the molecular weight and improving the processability of cis-1,4-polybutadiene
- Patent Title (中): 降低分子量和提高顺式-1,4-聚丁二烯加工性能的技术
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Application No.: US349276Application Date: 1994-12-05
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Publication No.: US5451646APublication Date: 1995-09-19
- Inventor: Kenneth F. Castner
- Applicant: Kenneth F. Castner
- Applicant Address: OH Akron
- Assignee: The Goodyear Tire & Rubber Company
- Current Assignee: The Goodyear Tire & Rubber Company
- Current Assignee Address: OH Akron
- Main IPC: C08F2/06
- IPC: C08F2/06 ; C08F4/60 ; C08F4/70 ; C08F36/06 ; C08F136/06
Abstract:
Cis-1,4-polybutadiene can be synthesized by polymerizing 1,3-butadiene monomer with a three component nickel catalyst system containing (a) an organonickel compound, (b) an organoaluminum compound, and (c) a fluorine containing compound. However, the molecular weight of the cis-1,4-polybutadiene prepared is typically too high to be utilized as a non-oil extended rubber. This invention is based upon the discovery that para-styrenated diphenylamine acts to reduce the molecular weight and to improve the processability of cis-1,4-polybutadiene prepared with such nickel based catalyst systems. The use of para-styrenated diphenylamine as a modifier in such polymerizations does not change the microstructure of the cis-1,4-polybutadiene produced. Accordingly, the present invention specifically discloses a process for producing cis-1,4-polybutadiene having a reduced molecular weight and improved processability which comprises polymerizing 1,3-butadiene in the presence of (a) an organonickel compound, (b) an organoaluminum compound, (c) a fluorine containing compound, and (d) para-styrenated diphenylamine; wherein the organoaluminum compound and the fluorine containing compound are brought together in the presence of the para-styrenated diphenylamine. Since para-styrenated diphenylamine is an excellent antidegradant, it also provides the rubber synthesized in its presence with antioxidant protection.
Public/Granted literature
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