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US5463160A Skeletal isomerization of n-pentenes to isopentene on pretreated zeolites 失效
在预处理的沸石上正己烯对异戊烯的骨架异构化

Skeletal isomerization of n-pentenes to isopentene on pretreated zeolites
摘要:
The selective conversion by skeletal isomerization over steam pretreated ferrierite zeolite-based catalysts having pore sizes of at least about 4.2 Angstroms and a pore structure characterized by intersecting 10-MR and 8-MR channels. The steam pretreated ferrierite zeolite-based catalysts have sufficient acidity to catalyze the skeletal isomerization of normal olefins. The catalysts can be used to produce isoolefins for reaction with alcohols in integrated processes to produce tertiary amyl methyl ethers such as TAME.
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