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US5494941A Preparation of chlorofluorocarbon-free flexible polyurethane foams using diphenylmethane diisocyanate-based polyisocyanate mixtures containing urethane groups, and modified polyisocyanate mixtures of the type 失效
使用含有氨基甲酸酯基团的二苯基甲烷二异氰酸酯基聚异氰酸酯混合物和类型的改性多异氰酸酯混合物制备不含氟氯化碳的柔性聚氨酯泡沫体

Preparation of chlorofluorocarbon-free flexible polyurethane foams using
diphenylmethane diisocyanate-based polyisocyanate mixtures containing
urethane groups, and modified polyisocyanate mixtures of the type
摘要:
The invention relates to a process for the preparation of CFC-free, flexible polyurethane foams or molded foams by reactingA) liquid polyisocyanate mixtures containing bonded urethane groups and having a content of NCO groups of from 20 to 30% by weight, these mixtures themselves being prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl-polymethylene polyisocyanates (crude diphenylmethane diisocyanate) with a polyether-polyol mixture, having a hydroxyl number of from 120 to 25, of at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene-polyoxyethylene glycol having a content of ethylene oxide units of from 90 to 10% by weight or by reacting 4,4'-diphenylmethane diisocyanate (diphenylmethyl diisocyanate) or an diphenylmethane diisocyanate isomer mixture with said polyether-polyol mixture to give an NCO-containing quasi-prepolymer and diluting this quasi-prepolymer with crude diphenylmethane diisocyanate, withB) relatively high-molecular-weight polyhydroxyl compounds.
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