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US5504048A Addition of lithium compounds to Ziegler-Natta catalysts for increased molecular weight in polyolefins 失效
向齐格勒 - 纳塔催化剂中加入锂化合物以增加聚烯烃中的分子量

Addition of lithium compounds to Ziegler-Natta catalysts for increased
molecular weight in polyolefins
摘要:
This invention relates to a conventional supported heterogeneous Ziegler-Natta catalyst for the polymerization of olefins. It has been found that adding a lithium compound to a transition metal catalyst component and then adding an organoaluminum co-catalyst and an organosilicon electron donor produces a catalyst which yields polymer with increased molecular weight. The lithium compound is of the general formula LiCp wherein Cp is a cyclopentadienyl or substituted cyclopentadienyl and is preferably lithium cyclopentadienide or lithium indene. Preferably, the molar ratio of lithium compound/transition metal is at least 0.2.
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