发明授权
US5504048A Addition of lithium compounds to Ziegler-Natta catalysts for increased
molecular weight in polyolefins
失效
向齐格勒 - 纳塔催化剂中加入锂化合物以增加聚烯烃中的分子量
- 专利标题: Addition of lithium compounds to Ziegler-Natta catalysts for increased molecular weight in polyolefins
- 专利标题(中): 向齐格勒 - 纳塔催化剂中加入锂化合物以增加聚烯烃中的分子量
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申请号: US71438申请日: 1993-06-02
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公开(公告)号: US5504048A公开(公告)日: 1996-04-02
- 发明人: Edwar S. Shamshoum , Christopher Bauch
- 申请人: Edwar S. Shamshoum , Christopher Bauch
- 申请人地址: TX Dallas
- 专利权人: Fina Technology, Inc.
- 当前专利权人: Fina Technology, Inc.
- 当前专利权人地址: TX Dallas
- 主分类号: B01J31/02
- IPC分类号: B01J31/02 ; B01J31/12 ; B01J31/14 ; B01J31/22 ; B01J31/38 ; C08F4/64 ; C08F4/659 ; C08F10/00 ; C08F10/06 ; B01J31/00
摘要:
This invention relates to a conventional supported heterogeneous Ziegler-Natta catalyst for the polymerization of olefins. It has been found that adding a lithium compound to a transition metal catalyst component and then adding an organoaluminum co-catalyst and an organosilicon electron donor produces a catalyst which yields polymer with increased molecular weight. The lithium compound is of the general formula LiCp wherein Cp is a cyclopentadienyl or substituted cyclopentadienyl and is preferably lithium cyclopentadienide or lithium indene. Preferably, the molar ratio of lithium compound/transition metal is at least 0.2.
公开/授权文献
- US5931330A Open head container cover 公开/授权日:1999-08-03
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