发明授权
- 专利标题: Process for the continuous preparation of aryl carbonates
- 专利标题(中): 连续制备碳酸芳基酯的方法
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申请号: US206575申请日: 1994-03-04
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公开(公告)号: US5523451A公开(公告)日: 1996-06-04
- 发明人: Johann Rechner , Norbert Schon , Paul Wagner , Hans-Josef Buysch , Stephan Kabelac
- 申请人: Johann Rechner , Norbert Schon , Paul Wagner , Hans-Josef Buysch , Stephan Kabelac
- 申请人地址: DEX Leverkusen
- 专利权人: Bayer Aktiengesellschaft
- 当前专利权人: Bayer Aktiengesellschaft
- 当前专利权人地址: DEX Leverkusen
- 优先权: DEX4307852.4 19930312; DEX4316428.5 19930517
- 主分类号: B01J31/12
- IPC分类号: B01J31/12 ; B01J10/00 ; B01J19/24 ; C07B61/00 ; C07C68/06 ; C07C68/08 ; C07C69/96
摘要:
Organic carbonates which contain at least one aromatic ester group can be obtained continuously from carbonates, which contain at least one aliphatic ester group, and a phenolic compound in the presence of a transesterification catalyst known per se in that the reaction is carried out in a bubble column reactor or in a cascade of at least two bubble column reactors in such a way that the phenolic compound is metered into the first bubble column and the carbonate containing at least one aliphatic ester group is metered into each individual bubble column, but preferably only into the last bubble column. The carbonate containing at least one aromatic ester group is taken off in the liquid state from the last bubble column. Volatile reaction products, for example eliminated alcohol or a dialkyl carbonate are taken off at the upper end of each individual bubble column, preferably at the upper end of the first bubble column.
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