发明授权
- 专利标题: Method for hydrogenation of metathesis polymers
- 专利标题(中): 复分解聚合物的氢化方法
-
申请号: US542654申请日: 1995-10-13
-
公开(公告)号: US5539060A公开(公告)日: 1996-07-23
- 发明人: Yasuo Tsunogae , Hideharu Mizuno , Teiji Kohara , Tadao Natsuume
- 申请人: Yasuo Tsunogae , Hideharu Mizuno , Teiji Kohara , Tadao Natsuume
- 申请人地址: JPX Tokyo
- 专利权人: Nippon Zeon Co., Ltd.
- 当前专利权人: Nippon Zeon Co., Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX5-208509 19930730; JPX5-269619 19930930
- 主分类号: C08G61/08
- IPC分类号: C08G61/08 ; C08F8/04
摘要:
The present invention provides a method for hydrogenating a metathesis polymer solution obtained by polymerization in the presence of a metathesis polymerization catalyst comprising (a) the catalyst component of a transition metal compound and (b) the co-catalyst component of a metal compound by bringing the above solution into contact with hydrogen, without adding an inactivating agent for the metathesis polymerization catalyst, that is, with the solution left to contain the catalyst, in the presence of a hydrogenation catalyst comprising a transition metal compound (c) and a reductive metal compound (d) and if necessary by adding an acid-binding compound. According to this method, both addition of the inactivating agent and removal of the metathesis polymerization catalyst are not necessary, and also the hydrogenation can be carried out at a lower temperature and under a lower pressure than in hydrogenation with a supported-type catalyst, so that the efficiency of production of the hydrogenated product is excellent. Besides, even if tungsten hexachloride (WCl.sub.6), etc. are used as the catalyst component, an effect of preventing a hydrogenation reactor from corrosion by a hydrogen halide, can be obtained.
公开/授权文献
- US4686183A Process for the manufacture of p-menth-8-ene-1,2-diol 公开/授权日:1987-08-11
信息查询