发明授权
- 专利标题: Process for producing terephthalic acid
- 专利标题(中): 对苯二甲酸生产方法
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申请号: US550400申请日: 1995-10-30
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公开(公告)号: US5567842A公开(公告)日: 1996-10-22
- 发明人: Yoshiaki Izumisawa , Tukasa Kawahara , Akihiko Toyosawa
- 申请人: Yoshiaki Izumisawa , Tukasa Kawahara , Akihiko Toyosawa
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Chemical Corporation
- 当前专利权人: Mitsubishi Chemical Corporation
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX6-282178 19941116; JPX6-282179 19941116
- 主分类号: C07C51/43
- IPC分类号: C07C51/43
摘要:
A process for producing terephthalic acid, which comprises dissolving crude terephthalic acid in an aqueous medium, contacting it with a platinum group metal catalyst for purification under a temperature condition of from 260.degree. to 320.degree. C., crystallizing terephthalic acid from the aqueous solution of terephthalic acid by cooling the aqueous solution stepwise in a plurality of crystallizers connected in series, in such a manner that in a first crystallization zone, the crystallization temperature is adjusted to a level within a range of from 240.degree. to 260.degree. C. and agitating is carried out by impeller with a power requirement of impeller within a range of from 0.4 to 10 kw/m.sup.3, and then, in a second crystallization zone, the crystallization temperature is adjusted to a level within a range of from 180.degree. to 230.degree. C., which is lower by from 20.degree. to 60.degree. C. than the crystallization temperature in the first crystallization zone, followed by solid-liquid separation, and drying the separated terephthalic acid crystals to obtain terephthalic acid particles wherein the proportion of particles having particle sizes exceeding 210 .mu.m is at most 10 wt %.
公开/授权文献
- US5077472A Ion mirror for a time-of-flight mass spectrometer 公开/授权日:1991-12-31
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