发明授权
- 专利标题: Method for drying polyamide and method for solid-phase polymerization of polyamide
- 专利标题(中): 聚酰胺干燥方法及聚酰胺固相聚合方法
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申请号: US511679申请日: 1995-08-07
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公开(公告)号: US5576415A公开(公告)日: 1996-11-19
- 发明人: Kazumi Tanaka
- 申请人: Kazumi Tanaka
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX5-214622 19940908
- 主分类号: C08G69/28
- IPC分类号: C08G69/28 ; C08G69/30 ; C08G69/46
摘要:
There are disclosed a method for drying and a method for solid-phase polymerizing a crystallizable polyamide being in an amorphous state which comprises regulating the moisture concentration in the polyamide at its glass transition temperature to at least 0.15% by weight as determined by Karl Fisher titration; heating the polyamide thus regulated at a pressure of at least one arm without reducing the moisture to crystallize the same up to a crystallinity of at least 15% and; further heating the polyamide thus crystallized at a temperature lower than its melting point under reduced pressure with a batchwise heating apparatus. It is made possible according to the method for drying or the method for solid-phase polymerizing the crystallizable polyamide to effect its crystallization without causing tackified sticking or solidified sticking of the polyamide, along with drying or solid-phase polymerization with single apparatus and process, while dispensing with any pretreatment such as surface modification and preliminary treatment equipment intended for crystallization.
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