发明授权
- 专利标题: Process for the preparation of tapered copolymers via in situ dispersion
- 专利标题(中): 通过原位分散制备锥形共聚物的方法
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申请号: US352938申请日: 1994-12-09
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公开(公告)号: US5614579A公开(公告)日: 1997-03-25
- 发明人: David M. Roggeman , James E. Hall
- 申请人: David M. Roggeman , James E. Hall
- 申请人地址: JPX Tokyo
- 专利权人: Bridgestone Corporation
- 当前专利权人: Bridgestone Corporation
- 当前专利权人地址: JPX Tokyo
- 主分类号: C08F297/04
- IPC分类号: C08F297/04 ; C08K3/02
摘要:
A process is provided for the preparation of tapered copolymers by the nonaqueous dispersion polymerization of a mixture of 30 to 70% by weight of a conjugated diolefin monomer, preferably butadiene, and 30 to 70% by weight of a vinyl substituted aromatic monomer, preferably styrene, in a liquid hydrocarbon dispersion medium with an anionic initiator catalyst system in the presence of a block copolymeric dispersing agent. At least one block of the dispersing agent is prepared prior to the dispersion polymerization reaction and at least one block of the dispersing agent is prepared in situ during the dispersion copolymerization. The block of the dispersing agent that is prepared in situ has the polymer structure of the tapered copolymer.
公开/授权文献
- US4478353A Vendor control system 公开/授权日:1984-10-23
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