发明授权
US5654248A Catalyst for polymerizing alpha-olefins and process for polymerization
失效
用于聚合α-烯烃的催化剂和聚合方法
- 专利标题: Catalyst for polymerizing alpha-olefins and process for polymerization
- 专利标题(中): 用于聚合α-烯烃的催化剂和聚合方法
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申请号: US433545申请日: 1995-05-02
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公开(公告)号: US5654248A公开(公告)日: 1997-08-05
- 发明人: Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
- 申请人: Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX61-198037 19860826; JPX61-198038 19860826; JPX61-203638 19860901; JPX62-34591 19870219
- 主分类号: C08F4/02
- IPC分类号: C08F4/02 ; C08F4/60 ; C08F4/64 ; C08F4/659 ; C08F4/6592 ; C08F10/10 ; C08F110/02 ; B01J31/00 ; B01J37/00
摘要:
A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.
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