发明授权
US5658997A Process for polymerizing propylene by using a novel metallocene catalyst
失效
通过使用新的茂金属催化剂聚合丙烯的方法
- 专利标题: Process for polymerizing propylene by using a novel metallocene catalyst
- 专利标题(中): 通过使用新的茂金属催化剂聚合丙烯的方法
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申请号: US474658申请日: 1995-06-07
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公开(公告)号: US5658997A公开(公告)日: 1997-08-19
- 发明人: Daisuke Fukuoka , Takashi Tashiro , Koji Kawaai , Junji Saito , Takashi Ueda , Yoshihisa Kiso , Junichi Imuta , Terunori Fujita , Masatoshi Nitabaru , Masayasu Yoshida
- 申请人: Daisuke Fukuoka , Takashi Tashiro , Koji Kawaai , Junji Saito , Takashi Ueda , Yoshihisa Kiso , Junichi Imuta , Terunori Fujita , Masatoshi Nitabaru , Masayasu Yoshida
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人: Mitsui Petrochemical Industries, Ltd.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX5-136253 19930607; JPX5-238561 19930924; JPX5-250742 19931006; JPX5-298744 19931129; JPX5-298745 19931129; JPX5-25548 19940223
- 主分类号: C07C45/46
- IPC分类号: C07C45/46 ; C07C49/67 ; C07C49/697 ; C07F17/00 ; C08F4/60 ; C08F4/602 ; C08F4/619 ; C08F4/6192 ; C08F4/64 ; C08F4/642 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F10/06 ; C08F110/06 ; C08F210/06 ; C08F210/16
摘要:
The novel transition metal compound of the invention is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like. An olefin polymerization catalyst component of the present invention comprises the aforementioned transition metal compound. An olefin polymerization catalyst of the present invention comprises the aforementioned olefin polymerization catalyst component. The propylene homopolymer, the propylene copolymer and the propylene elastomer according to the present invention have such properties that the triad tacticity of propylene units chain is high, a proportion of the inversely units based on the 2,1-insertion of propylene monomer is in the specific range, and the intrinsic viscosity [.eta.], as measured in decahydronaphthalene at 135.degree. C., is in the specific range.
公开/授权文献
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