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US5661096A Catalysts and cocatalysts for the preparation of polyolefins 失效
用于制备聚烯烃的催化剂和助催化剂

Catalysts and cocatalysts for the preparation of polyolefins
Abstract:
In the case of Ziegler catalysts based on a metallocene as the transition metal component and an aluminoxane as the activator, preactivation of the metallocene with the aluminoxane results in a considerable increase in the activity of the catalyst system. Furthermore, 1-olefin polymers of a high degree of isotacticity and having compact, spherical particles, a very narrow particle size distribution and a high bulk density are obtained by means of a catalyst system of this type.
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