发明授权
- 专利标题: Method for producing aldehydes
- 专利标题(中): 醛的生产方法
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申请号: US568970申请日: 1995-12-07
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公开(公告)号: US5672766A公开(公告)日: 1997-09-30
- 发明人: Tomoyuki Mori , Masaki Takai , Tomohiko Inoue
- 申请人: Tomoyuki Mori , Masaki Takai , Tomohiko Inoue
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Chemical Corporation
- 当前专利权人: Mitsubishi Chemical Corporation
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX6-307707 19941212; JPX7-079052 19950404
- 主分类号: C07C45/50
- IPC分类号: C07C45/50
摘要:
A method for producing aldehydes, which comprises reacting an olefinic unsaturated compound with carbon monoxide and hydrogen for hydroformylation in the presence of a rhodium-phosphite complex catalyst to obtain a reaction product solution containing the rhodium-phosphite complex catalyst and an aldehyde product, and separating from the reaction product solution at least one component selected from the group consisting of carbon monoxide, hydrogen, an unreacted olefinic unsaturated compound, the aldehyde product, a solvent, a medium-boiling by-product and a high-boiling by-product by a separating operation, wherein at least one separating operation is carried out substantially in the absence of water, and the temperature and the residence time in the separating operation are selected to be within such ranges that value P calculated from the following formula (1) would be at most 1: P=5.0.times.10.sup.3 .times.exp�-5000/(T.sub.1 +273)!.times..theta.T.sub.1(1) where T.sub.1 is the maximum temperature (.degree.C.) in the separating operation, and .theta.T.sub.1 is the residence time (minutes) of the liquid in the separating operation.
公开/授权文献
- US3972183A Gas dissociation thermal power system 公开/授权日:1976-08-03
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