发明授权
- 专利标题: Aromatic dinitro and diamino intermediates
- 专利标题(中): 芳香二硝基和二氨基中间体
-
申请号: US453073申请日: 1995-05-26
-
公开(公告)号: US5710334A公开(公告)日: 1998-01-20
- 发明人: Yuko Ishihara , Mitsunori Matsuo , Keizaburo Yamaguchi , Akihiro Yamaguchi
- 申请人: Yuko Ishihara , Mitsunori Matsuo , Keizaburo Yamaguchi , Akihiro Yamaguchi
- 申请人地址: JPX Tokyo
- 专利权人: Mitsui Toatsu Chemicals, Inc.
- 当前专利权人: Mitsui Toatsu Chemicals, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX4-132081 19920525; JPX4-258004 19920928; JPX4-302270 19921112; JPX5-030082 19930219; JPX5-056977 19930317; JPX5-203871 19930818; JPX5-331996 19931227; JPX6-126128 19940608
- 主分类号: C07C201/12
- IPC分类号: C07C201/12 ; C07C205/45 ; C07C221/00 ; C07C225/22 ; C08G73/10 ; C08G73/12 ; C08J5/18 ; C08L79/08 ; C07C217/84 ; C07C217/90
摘要:
This invention relates to a novel thermoplastic and amorphous polyimide which is readily soluble in organic solvent, a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the thermoplastic polyimide and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition, a polyimide-based composite obtained by molding the above soluble and thermoplastic polyimide in combination with a fibrous reinforcement, and a fibrous reinforcement having a surface modified with the above polyimide. The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein m and n are individually an integer of 0 or 1, and R is ##STR2## The polyimide of the invention is essentially amorphous, excellent in melt flow stability in the decreased temperature as compared with conventionally known polyimide and has greatly improved processability. The polyimide of the invention obtained by using a novel aromatic diamino compound as a monomer can control various properties such as melt flow ability and solubility in solvents by side chains and not by principal chain of polyimide. Thus, excellent melt flow property and solubility in solvents can be obtained while maintaining high heat resistance and adhesive property which are derived from benzophenone structure of the diamino compound of the the invention.