Invention Grant
US5726115A Bridged bis-amino group 4 metal compounds in a catalyst composition for
the production of alpha-olefins
失效
用于生产α-烯烃的催化剂组合物中桥连的双氨基4金属化合物
- Patent Title: Bridged bis-amino group 4 metal compounds in a catalyst composition for the production of alpha-olefins
- Patent Title (中): 用于生产α-烯烃的催化剂组合物中桥连的双氨基4金属化合物
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Application No.: US615551Application Date: 1996-03-11
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Publication No.: US5726115APublication Date: 1998-03-10
- Inventor: Andrew David Horton , Jan De With
- Applicant: Andrew David Horton , Jan De With
- Applicant Address: TX Houston
- Assignee: Shell Oil Company
- Current Assignee: Shell Oil Company
- Current Assignee Address: TX Houston
- Priority: EPX98200570 19950308
- Main IPC: B01J31/12
- IPC: B01J31/12 ; B01J31/16 ; B01J31/18 ; C07F7/00 ; C07F7/10 ; C07F7/12 ; C07F7/22 ; C07F7/28 ; C07F7/30 ; C08F4/60 ; C08F4/643 ; C08F4/646 ; C08F4/659 ; C08F10/00 ; B01J31/00 ; C08F4/02 ; B04J37/00
Abstract:
A catalyst composition comprising a bis-amide compound represented by the formula ##STR1## wherein M is zirconium, hafnium or titanium; each N is a three coordinate nitrogen atom; each e is Si, Ge or Sn; each Z is, independently, a hydride or R; each R is, independently, a hydrocarbyl one or more carbon atoms of which may be substituted by an element selected from Si, O, P, N and S; L is a neutral Lewis base and m is a number from 0 to 2; or a dimer thereof and a second component. Preferably the second component is a compound which is capable of providing a bulky and labile anion �A!.sup.-, which anion is substantially non-coordinating under the reaction conditions and contains at least one boron atom. Also provided is a process for oligomerizing or co-oligomerizing alpha olefins in the presence of this catalyst composition.
Public/Granted literature
- US5087271A Partial oxidation process Public/Granted day:1992-02-11
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