发明授权
- 专利标题: High molecular weight homopolymers and copolymers of ethene
- 专利标题(中): 乙烯的高分子量均聚物和共聚物
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申请号: US954429申请日: 1992-09-30
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公开(公告)号: US5756627A公开(公告)日: 1998-05-26
- 发明人: Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
- 申请人: Hans Gropper , Guido Funk , Erich Kolk , Dieter Oeder
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DEX Ludwigshafen
- 主分类号: C08F4/02
- IPC分类号: C08F4/02 ; C08F4/18 ; C08F4/22 ; C08F4/24 ; C08F10/00 ; C08F110/02 ; C08F10/02
摘要:
The present invention relates to high molecular weight homopolymers and copolymers of ethene, which homopolymer or copolymer is obtained by polymerizing the monomer(s) at a temperature of from 70.degree. to 150.degree. C. and under a pressure of from 2 to 150 bar in contact witha chromium trioxide catalyst, (1) loading a support based on silicon dioxide with (2) either chromium trioxide or a chromium compound capable of being converted to chromium trioxide under the conditions of stage (3) below and then (3) heating the resulting intermediate in a gas stream containing oxygen, the support (1) being a special silica xerogel obtained by extracting not more than 30% of the water from a silica hydrogel by means of an alkanol, an alkanone or a mixture thereof followed by drying, comminution and fractional screening.