发明授权
- 专利标题: Process for selective hydrogenation of unsaturated polymers
- 专利标题(中): 不饱和聚合物的选择性氢化方法
-
申请号: US704656申请日: 1996-12-04
-
公开(公告)号: US5814710A公开(公告)日: 1998-09-29
- 发明人: Petri Rekonen , Nina Kopola , Salme Koskimies , Ove Andell , Marita Oksman
- 申请人: Petri Rekonen , Nina Kopola , Salme Koskimies , Ove Andell , Marita Oksman
- 申请人地址: FIX Provoo
- 专利权人: Neste Oy
- 当前专利权人: Neste Oy
- 当前专利权人地址: FIX Provoo
- 优先权: FIX941189 19940314
- 主分类号: C08C19/02
- IPC分类号: C08C19/02 ; C08F8/04
摘要:
The invention relates to the selective hydrogenation of unsaturated polymers, in particular elastomeric polymers which contain aromatic rings and carbon-carbon double rings, for example polymers prepared from styrene and butadiene. In this case, the polymer molecule contains internal and terminal-group double bonds, as well as unsaturated bonds in aromatic rings. According to the invention, only the unsaturated terminal and internal bonds are hydrogenated, whereby the thermal and weather resistance properties of the product are improved. Conventionally, hydrogenation has been performed by means of nickel or cobalt catalysts, but now it has been observed that a metallocene/alumoxane catalyst complex not only catalyzes the polymerization reaction of various olefinic compounds but also catalyzes the selective hydrogenation of unsaturated polymers, preferably styrene-butadiene-styrene block polymers.
公开/授权文献
- US5085864A Injectable formulation for lipophilic drugs 公开/授权日:1992-02-04
信息查询