发明授权
- 专利标题: Process for preparing lactate
- 专利标题(中): 制备乳酸盐的方法
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申请号: US698478申请日: 1996-08-15
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公开(公告)号: US5824818A公开(公告)日: 1998-10-20
- 发明人: Takafumi Abe , Toshiyuki Gotoh , Takako Uchiyama , Hirofumi Higuchi , Yoshikazu Shima , Kazuto Ikemoto
- 申请人: Takafumi Abe , Toshiyuki Gotoh , Takako Uchiyama , Hirofumi Higuchi , Yoshikazu Shima , Kazuto Ikemoto
- 申请人地址: JPX Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址: JPX Tokyo
- 优先权: JPX6-022385 19940221
- 主分类号: C07C67/20
- IPC分类号: C07C67/20 ; C07C69/66
摘要:
A process for preparing a lactate which includes: (a) preparing lactonitrile from prussic acid and acetaldehyde, (b) hydrating the lactonitrile to form lactamide, (c) forming the desired lactate and formamide from lactamide and formate (or methanol and carbon monoxide), (d) separating and collecting components, having a lower boiling point than that of lactate from the reaction liquid in step (c), by distillation under specified conditions, and (e) dehydrating formamide from step (d) to form prussic acid and recycling the prussic acid to step (a). Heretofore, lactates had been manufactured by forming lactonitrile (cyanohydrin) from acetaldehyde and prussic acid, and then esterifying lactonitrile with a mineral acid or the like. However, in this conventional process, ammonium salts were formed as by-products in an amount equal to that of the lactate. According to the present invention, a lactate can be efficiently manufactured on a commercial scale without forming a large amount of the ammonium salts as by-products. In particular, the yield of the lactate can be increased by controlling the formation of 2-formyloxy propionate and also a dimer of a lactate.
公开/授权文献
- US4558296A Sound damping devices 公开/授权日:1985-12-10
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