发明授权
- 专利标题: Process for the preparation of acetic acid from a synthesis gas of hydrogen and carbon monoxide
- 专利标题(中): 从氢气和一氧化碳的合成气中制备乙酸的方法
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申请号: US979527申请日: 1997-11-26
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公开(公告)号: US5840969A公开(公告)日: 1998-11-24
- 发明人: Finn Joensen
- 申请人: Finn Joensen
- 申请人地址: DKX Lyngby
- 专利权人: Haldor Topsoe A/S
- 当前专利权人: Haldor Topsoe A/S
- 当前专利权人地址: DKX Lyngby
- 优先权: DKX1361/96 19961129
- 主分类号: B01J31/28
- IPC分类号: B01J31/28 ; C07B61/00 ; C07C29/151 ; C07C41/01 ; C07C51/10 ; C07C51/12 ; C07C53/08 ; C07C67/36
摘要:
A process for the preparation of acetic acid product comprising, in a first catalytic step, conversion of a hydrogen and carbon monoxide containing synthesis gas to obtain a liquid process stream comprising methanol and, in a second catalytic step, carbonylation of the process stream with carbon monoxide to a product stream being rich in the acetic acid product in presence of catalytic effective amounts of a metal compound selected from Group VIII of the Periodic Table promoted with a halide compound, the improvement comprising the further steps of: (i) withdrawing from the carbonylation step a vent gas stream comprising carbon monoxide and residual amounts of acetic acid and halide compound; (ii) separating the vent gas stream into a liquid fraction containing a part of the residual amounts of acetic acid and part of the halide compound and a gaseous fraction with the carbon monoxide and remaining amounts of acetic acid and halide compound; (iii) recycling the liquid fraction to the carbonylation step; (iv) subjecting the gaseous fraction to liquid absorption to remove the acetic acid and halide compound in the gaseous fraction to obtain a carbon monoxide rich recycle stream; and (v) introducing the carbon monoxide rich recycle stream into the synthesis gas conversion step.
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