Invention Grant
US5880233A Process for the preparation of ethylene/(meth)acrylic acid copolymers
失效
制备乙烯/(甲基)丙烯酸共聚物的方法
- Patent Title: Process for the preparation of ethylene/(meth)acrylic acid copolymers
- Patent Title (中): 制备乙烯/(甲基)丙烯酸共聚物的方法
-
Application No.: US957321Application Date: 1997-11-06
-
Publication No.: US5880233APublication Date: 1999-03-09
- Inventor: Andreas Deckers , Eckard Schauss , Roger Klimesch , Wilhelm Weber
- Applicant: Andreas Deckers , Eckard Schauss , Roger Klimesch , Wilhelm Weber
- Applicant Address: DEX Ludwigshafen
- Assignee: BASF Aktiengesellschaft
- Current Assignee: BASF Aktiengesellschaft
- Current Assignee Address: DEX Ludwigshafen
- Main IPC: C08F2/00
- IPC: C08F2/00 ; C08F4/38 ; C08F210/02
Abstract:
Copolymers of ethylene with .alpha.,.beta.-unsaturated carboxylic acids are prepared at from 50.degree. to 250.degree. C. and from 500 to 5000 bar in a stirred autoclave having a length/diameter ratio greater than 5:1 by a process in which the monomer mixtures are fed into the autoclave in at least two part-streams, the first part-stream being passed into the autoclave at the beginning of the autoclave pipe and the second part-stream being introduced at a position which is a distance away from the beginning which corresponds to 25-50% of the total length and the amount of the .alpha.,.beta.-unsaturated carboxylic acids in the first part-stream is from 20 to 90% less than the average amount in the further part-streams and a peroxide polymerization initiator having a lower decomposition temperature, or a mixture of peroxide polymerization initiators having a lower average decomposition temperature, than that of the initiators in the further part-streams is passed in with the first part-stream.
Public/Granted literature
- US5319064A Thermotropic liquid crystalline poly(ester-amides) Public/Granted day:1994-06-07
Information query