发明授权
- 专利标题: Method for extending the pot life of an olefin metathesis polymerization reaction
- 专利标题(中): 延长烯烃易位聚合反应的适用期的方法
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申请号: US759018申请日: 1996-12-02
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公开(公告)号: US5939504A公开(公告)日: 1999-08-17
- 发明人: Charles S. Woodson, Jr. , Robert H. Grubbs
- 申请人: Charles S. Woodson, Jr. , Robert H. Grubbs
- 申请人地址: LA Monroe
- 专利权人: Advanced Polymer Technologies
- 当前专利权人: Advanced Polymer Technologies
- 当前专利权人地址: LA Monroe
- 主分类号: B01J31/22
- IPC分类号: B01J31/22 ; C08F4/80 ; C08G61/08
摘要:
Compositions and methods for catalyzing and controlling the rate of olefin metathesis reactions including Ring Opening Metathesis Polymerization (ROMP) reactions. The molding of polymer articles using ROMP polymers. The composition includes a Ruthenium or Osmium carbene complex catalyst and a gel modification additive. The Ruthenium or Osmium carbene complex catalyst having the formula ##STR1## where M may be Os or Ru; R and R.sup.1 may be the same or different and may be hydrogen or a substituent group including C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.1 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl and C.sub.1 -C.sub.20 alkylsulfinyl; X and X.sup.1 may be the same or different and may be any anionic ligand; and L and L.sup.1 may be the same or different and may be neutral electron donor. The gel modification additive may be a neutral electron donor or a neutral Lewis base including phosphine, sulfonated phosphine, phosphite, phosphinite, phosphonite, arsine, stibine, ether, amine, amide, sulfoxide, carboxyl, nitrosyl, pyridine, or thioether. The gel modification additive may be a trialkylphosphine or triarylphosphine. Examples of gel modification additives include P(cyclohexyl).sub.3, P(cyclopentyl).sub.3, P(isopropyl).sub.3, P(phenyl).sub.3, and pyridine.
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