发明授权
- 专利标题: Olefin polymerization catalyst
- 专利标题(中): 烯烃聚合催化剂
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申请号: US986183申请日: 1997-12-05
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公开(公告)号: US5990034A公开(公告)日: 1999-11-23
- 发明人: Takashi Nozaki
- 申请人: Takashi Nozaki
- 申请人地址: JPX Osaka
- 专利权人: Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人: Asahi Kasei Kogyo Kabushiki Kaisha
- 当前专利权人地址: JPX Osaka
- 优先权: JPX8-340415 19961206
- 主分类号: C08F4/02
- IPC分类号: C08F4/02 ; C08F4/60 ; C08F4/658 ; C08F10/00 ; C08F110/02 ; C08F210/16 ; B01J31/00 ; B01J37/00
摘要:
An olefin polymerization catalyst comprising (A) a solid catalyst component and (B) an organometallic compound component. The solid catalyst component (A) is prepared by a process comprising the steps of:(I) obtaining a solid (A-1) by reacting:(i) an organomagnesium component soluble in a hydrocarbon solvent and represented by the formula (M.sup.1).sub..alpha. (Mg).sub..beta. (R.sup.1).sub.p (R.sup.2).sub.q (OR.sup.3).sub.r ; and(ii) an Si--H bond-containing chlorosilane compound represented by the formula: H.sub.a SiCl.sub.b R.sup.4.sub.4-(a+b), in a ratio of from 0.01 to 100 mol (ii) per mol (i);(II) reacting the solid (A-1) with an alcohol (A-2) in a ratio of from 0.05 to 20 mol of the alcohol per mol of C--Mg bonds contained in the solid (A-1), to form a reaction product; and(III) reacting the reaction product with a titanium compound (A-4). The solid catalyst component (A) is adjusted to have an alkoxy group/titanium molar ratio of 2.4 or lower and an alkoxy group/magnesium molar ratio of 0.15 or lower.
公开/授权文献
- US5267386A Method of securing a member to a heat softenable material 公开/授权日:1993-12-07