The crystallinity of an amorphous precursor polycarbonate is enhanced by contact in the liquid or vapor state with a non-solvent which may be water, an alkanol or a mixture thereof and which is dialkyl carbonate-free. Contact temperatures are at least about 75.degree. C. and are further defined by the relationshipT.sub.c .gtoreq.T.sub.b -z,wherein T.sub.c is the contact temperature, T.sub.b is the boiling point of the non-solvent at the contact pressure employed (both in degrees C.) and z is a constant whose value is 60.