发明授权
US6034026A Procatalyst for ethylene polymer production, method for its preparation
and use
失效
用于乙烯聚合物生产的主催化剂,其制备和使用方法
- 专利标题: Procatalyst for ethylene polymer production, method for its preparation and use
- 专利标题(中): 用于乙烯聚合物生产的主催化剂,其制备和使用方法
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申请号: US14674申请日: 1998-01-28
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公开(公告)号: US6034026A公开(公告)日: 2000-03-07
- 发明人: Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
- 申请人: Thomas Garoff , Solveig Johansson , Ulf Palmqvist , Daniel Lindgren , Marita Sutela , Paivi Waldvogel , Arja Kostiainen
- 申请人地址: FIX Porvoo
- 专利权人: Borealis Polymers OY
- 当前专利权人: Borealis Polymers OY
- 当前专利权人地址: FIX Porvoo
- 优先权: FIX942949 19940620
- 主分类号: C08F4/654
- IPC分类号: C08F4/654 ; B01J37/00 ; C08F4/02 ; C08F4/64 ; C08F4/646 ; C08F4/651 ; C08F4/655 ; C08F4/658 ; C08F10/00 ; C08F10/02 ; C08F110/02 ; C08F110/06 ; B01J31/00
摘要:
The invention relates to a process for the preparation of a high activity procatalyst for the production of ethylene polymers. The process according to the present invention comprises the following steps:(a) contacting the inorganic support with an alkyl metal chloride which is soluble in non-polar hydrocarbon solvents, and has the formula(R.sub.n MeCl.sub.3-n).sub.m (1)wherein R is a C.sub.1 -C.sub.20 aklyl group, Me is a metal of group III(13) of the periodic table, n=1 or 2 and m=1 or 2, to give a first reaction product,(b) contacting said first reaction product with a compound or mixture containing hydrocarbyl and hydrocarbyl oxide linked to magnesium which is soluble in non-polar hydrocarbon solvents, to give a second reaction product, and(c) contacting said second reaction product with a titanium compound which contains chlorine, having the formulaCl.sub.x Ti(OR.sup.IV).sub.4-x (2)wherein R.sup.IV is a C.sub.2 -C.sub.20 hydrocarbyl group and x is 3 or 4, to give said procatalyst.
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