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US6048945A Graft polymers comprising polymers, containing alkylene oxide units, and ethylenically unsaturated compounds, their preparation and their use 失效
包含含有烯化氧单元的聚合物和烯键式不饱和化合物的接枝聚合物,其制备及其用途

Graft polymers comprising polymers, containing alkylene oxide units, and
ethylenically unsaturated compounds, their preparation and their use
摘要:
A graft polymer obtained by free radically polymerizing:(A) a monomer or monomer mixture comprising:(a) from 10-100% by weight of a N-vinylcarboxamide of the formula: ##STR1## where R.sup.1 and R.sup.2 are each H or C.sub.1 -C.sub.6 -alkyl, (b) from 0-90% by weight of at least one other monoethylenically unsaturated monomer which is copolymerizable with (a), and(c) from 0-5% by weight of at least one monomer having at least two ethylenically unsaturated nonconjugated double bonds in the molecule, in the presence of(B) a polytetrahydrofuran or a polymer which contains at least 3 units of a C.sub.2 -C.sub.4 alkylene oxide and is a hornopolymer of C.sub.2-4 -alkylene oxide having two free terminal OH groups or random or block copolymers of C.sub.2-4 -alkylene oxides having two free terminal OH groups or the reaction products of C.sub.2-4 -alkylene oxides with phenols, amines or fatty carboxylic acids, in a weight ratio (A):(B) ranging from 95:5 to 10:80, some or all of the amide groups having been eliminated by hydrolysis.
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