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US6054407A Peroxo-containing metal complexes having amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation catalysts 失效
具有氧化胺,氧化膦,氧化砷,吡啶N-氧化物或吡啶配体的含氧氧化物的金属络合物作为环氧化催化剂

Peroxo-containing metal complexes having amine oxide, phosphine oxide,
arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation
catalysts
摘要:
Olefins can be epoxidized using catalysts I ##STR1## where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements,L.sup.1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII,L.sup.2 is a customary auxiliary ligand or a further ligand L.sup.1 or a free coordination site,X is oxo oxygen or an imido ligand,m is 1 or 2, andn is 1, 2 or 3.
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