发明授权
US6054407A Peroxo-containing metal complexes having amine oxide, phosphine oxide,
arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation
catalysts
失效
具有氧化胺,氧化膦,氧化砷,吡啶N-氧化物或吡啶配体的含氧氧化物的金属络合物作为环氧化催化剂
- 专利标题: Peroxo-containing metal complexes having amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation catalysts
- 专利标题(中): 具有氧化胺,氧化膦,氧化砷,吡啶N-氧化物或吡啶配体的含氧氧化物的金属络合物作为环氧化催化剂
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申请号: US29737申请日: 1998-03-11
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公开(公告)号: US6054407A公开(公告)日: 2000-04-25
- 发明人: Michael Schulz , Joaquim Henrique Teles , Jorg Sundermeyer , Gunter Wahl
- 申请人: Michael Schulz , Joaquim Henrique Teles , Jorg Sundermeyer , Gunter Wahl
- 申请人地址: DEX Ludwigshafen
- 专利权人: BASF Aktiengesllschaft
- 当前专利权人: BASF Aktiengesllschaft
- 当前专利权人地址: DEX Ludwigshafen
- 优先权: DEX19533331 19950911
- 主分类号: B01J31/16
- IPC分类号: B01J31/16 ; B01J31/18 ; B01J31/22 ; C07B61/00 ; C07D301/06 ; C07D301/12 ; C07D303/04 ; B01J31/32 ; B01J31/34 ; B01J31/36 ; B01J31/38
摘要:
Olefins can be epoxidized using catalysts I ##STR1## where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements,L.sup.1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII,L.sup.2 is a customary auxiliary ligand or a further ligand L.sup.1 or a free coordination site,X is oxo oxygen or an imido ligand,m is 1 or 2, andn is 1, 2 or 3.
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