发明授权
US6084113A Complexes containing tris-(hydroxyalkyl)-phosphines as ligands for telomerizations, as catalysts and new complexes containing tris-(hydroxyalkyl)-phosphines 失效
含有三 - (羟基烷基)膦作为调聚配体的配合物,作为催化剂和含有三 - (羟基烷基) - 膦的新络合物

Complexes containing tris-(hydroxyalkyl)-phosphines as ligands for
telomerizations, as catalysts and new complexes containing
tris-(hydroxyalkyl)-phosphines
摘要:
In a process for the telomerization of dienes with nucleophiles in a liquid two-phase system, use is made as catalysts of complexes comprising a transition metal as central atom and at least one tris-(hydroxyalkyl)-phosphine or -phosphine oxide as ligand. The use as catalysts of compounds comprising a transition metal as central atom and at least one tris-(hydroxy-C.sub.2 -C.sub.5 -alkyl)-phosphine or -phosphine oxide as ligand, new compounds of this type and aqueous solutions of such compounds are likewise described.
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