发明授权
- 专利标题: Polymeric supported catalysts for olefin polymerization
- 专利标题(中): 用于烯烃聚合的聚合载体催化剂
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申请号: US092752申请日: 1998-06-05
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公开(公告)号: US6100214A公开(公告)日: 2000-08-08
- 发明人: John F. Walzer, Jr. , Anthony J. Dias , Jean M J Frechet , Stephen B. Roscoe
- 申请人: John F. Walzer, Jr. , Anthony J. Dias , Jean M J Frechet , Stephen B. Roscoe
- 申请人地址: TX Houston
- 专利权人: Exxon Chemical Patents Inc.
- 当前专利权人: Exxon Chemical Patents Inc.
- 当前专利权人地址: TX Houston
- 主分类号: C08F4/02
- IPC分类号: C08F4/02 ; C08F4/619 ; C08F4/6192 ; C08F4/64 ; C08F4/642 ; C08F4/643 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F210/16 ; B01J31/00 ; B01J37/00 ; C08F4/44 ; C08F4/60
摘要:
The described invention provides a low fouling, high particle density polymerization process and an olefin polymerization catalyst composition comprising the reaction product of a) an organic polymeric support i) having a surface area of from about 1 to 10 m.sup.2 /g and ii) functionalized with an acidic proton-containing ammonium salt of a non-coordinating anion, and b) an organometallic transition metal compound having ancillary ligands, at least one labile ligand capable of abstraction by protonation by said ammonium salt and at least one labile ligand into which an olefinic monomer can insert for polymerization. In a preferred embodiment, the polymeric support has a surface area of .ltoreq.10 m.sup.2 /g and is particularly suitable for use with high activity organometallic, transition metal catalyst compounds.