A vaporization/pressurization module employs a porous member having a low thermal conductivity and a substantially uniform, small pore size. Liquid feed is introduced to the porous member and is heated, vaporized, and pressurized within and/or on a surface of the porous member to produce a vapor jet having a pressure higher than that of the liquid feed. A substantially vapor impermeable barrier facilitates accumulation and pressurization of the vapor, which is released from the module as a pressurized vapor jet from one or more restricted passages. The vaporization/pressurization module is especially useful for liquid fuel combustion applications.