An electrochemical cell, and an associated process, wherein the cell includes a controlled electrode surface comprising an electrode with a metallic current collector having a surface, an electrolyte and a reduced additive. The invention further includes a passivating layer at the interface between the metallic current collector and the electrolyte. The passivating layer includes the reduced additive. This passivating layer substantially precludes contact between electrolyte solvent and surface of the metallic current collector to, in turn, substantially prevent gas formation within the cell, which would otherwise result from decomposition of the solvent upon contact with the surface of the metallic current collector. Also, the reduced additive will likewise be substantially precluded from generating a gas upon its decomposition.