发明授权
US06169198A Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation 失效
通过催化氢化法生产单烯烃C5-单腈混合物的方法

  • 专利标题: Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation
  • 专利标题(中): 通过催化氢化法生产单烯烃C5-单腈混合物的方法
  • 申请号: US09463820
    申请日: 2000-02-01
  • 公开(公告)号: US06169198A
    公开(公告)日: 2001-01-02
  • 发明人: Jakob FischerWolfgang Siegel
  • 申请人: Jakob FischerWolfgang Siegel
  • 优先权: DE19733682 19970804
  • 主分类号: C07C25310
  • IPC分类号: C07C25310
Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation
摘要:
A process for preparing mixtures of monoolefinic C5 mononitriles with nonconjugated C═C and C≡N bonds by catalytic hydrocyanation of 1,3-butadiene or a 1,3-butadiene-containing hydrocarbon mixture, wherein the hydrocyanation takes place in the presence of a catalyst which comprises at least one metallocene-phosphorus(III)-nickel(0) complex which comprises at least one monodentate or bidentate metallocene-phosphorus(III) ligand of the formula I or salts and mixtures thereof.
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