发明授权
- 专利标题: Agglomerated particles of water-swellable addition polymers, preparation thereof and use thereof
- 专利标题(中): 水溶胀性加成聚合物的聚集颗粒,其制备及其用途
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申请号: US08894373申请日: 1997-08-22
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公开(公告)号: US06174946B1公开(公告)日: 2001-01-16
- 发明人: Martin R{umlaut over (u)}benacker , Reinhard Schneider , J{umlaut over (u)}rgen Nieberle , Harald Meyer , Heinrich Hartmann
- 申请人: Martin R{umlaut over (u)}benacker , Reinhard Schneider , J{umlaut over (u)}rgen Nieberle , Harald Meyer , Heinrich Hartmann
- 优先权: DE19506287 19950223
- 主分类号: C08J312
- IPC分类号: C08J312
摘要:
Agglomerated particles of water-swellable addition polymers, the agglomerated particles having an average particle diameter of from 20 to 5000 &mgr;m and consisting of primary particles having an average particle diameter of from 0.1 to 15 &mgr;m, being preparable by polymerization of water-soluble monomers in the presence of from 1′ to 10% by weight of a regulator and at least 2000 ppm, each based on the monomers, of a crosslinking agent in the manner of a water-in-oil polymerization and subsequent azeotropic removal of water from the water-in-oil polymer emulsions, containing the primary particles, in the presence of agglomerating polyalkylene glycols which (a) are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids, and (b) contain at least 2 polymerized alkylene oxide units, and disintegrating into the primary particles on introduction into an aqueous medium, processes for preparing the agglomerated polymer particles and use of the agglomerated particles as thickeners for print pastes.
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