发明授权
- 专利标题: Polymer fluorescent substance and organic electroluminescence device
- 专利标题(中): 聚合物荧光物质和有机电致发光器件
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申请号: US08912336申请日: 1997-08-18
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公开(公告)号: US06207301B1公开(公告)日: 2001-03-27
- 发明人: Toshihiro Ohnishi , Takanobu Noguchi , Shuji Doi
- 申请人: Toshihiro Ohnishi , Takanobu Noguchi , Shuji Doi
- 优先权: JP8-220068 19960821
- 主分类号: H05B3314
- IPC分类号: H05B3314
摘要:
A polymeric fluorescent substance having visible fluorescence in a solid state and a polystyrene-reduced number-average molecular weight of 103 to 107, which contains at least one repeating unit represented by the following formula (1), —Ar1—CR1═CR2— (1) wherein the sum of the repeating unit is from 10 to 100 mol % of the total number of the repeating units, Ar1 represents an arylene group having 4 to 20 carbon atoms taking part in conjugated bonds and containing at least one substituent represented by the following formula (2) as a nuclear substituent, or a heterocyclic compound group, having 4 to 20 carbon atoms taking part in conjugated bonds, and containing at least one substituent represented by the following formula (2) as a nuclear substituent; and R1 and R2 independently represent a group selected from the group consisting of hydrogen, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, a heterocyclic compound group having 4 to 20 carbon atoms and a cyano group, —(X)m—(CH2)n—Ar2 (2) wherein Ar2 represents a group selected from the group consisting of an aryl group and having 4 to 20 carbon atoms taking part in conjugated bonds, a heterocyclic compound group, having 4 to 20 carbon atoms taking part in the conjugated bonds, and an aliphatic cyclic hydrocarbon compound group having 6 to 20 carbon atoms constituting the ring; X represents O or S; m represents 0 or 1; and n represents an integer of 2 to 10. The polymeric fluorescent substance is excellent as a material for organic EL devices because of strong fluorescence and good thermal stability. Furthermore, an organic EL device using the polymeric fluorescent substance can be preferably used as a flat light source for back light or a device such as a flat panel display and the like because it is easily produced and exhibits excellent light emitting characteristics and a heat resistance.
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