发明授权
US06211110B1 Bridged metallocene complex for the (co)polymerization of olefins
有权
用于烯烃((共))聚合的桥接茂金属络合物
- 专利标题: Bridged metallocene complex for the (co)polymerization of olefins
- 专利标题(中): 用于烯烃((共))聚合的桥接茂金属络合物
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申请号: US09262318申请日: 1999-03-04
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公开(公告)号: US06211110B1公开(公告)日: 2001-04-03
- 发明人: Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
- 申请人: Roberto Santi , Giampietro Borsotti , Gianfranco Longhini , Paolo Biagini , Antonio Proto , Francesco Masi , Viviano Banzi
- 优先权: ITMI98A0479 19980310
- 主分类号: B01J2100
- IPC分类号: B01J2100
摘要:
A “bridged” bis-cyclopentadienyl complex which can be advantageously used for the formation of a catalytic system active in the (co)polymerization of ethylene and other &agr;-olefins is represented by means of the following formula (II): wherein: M represents a metal selected from titanium, zirconium or hafnium; A′ and A″ each independently represent an anion containing an &eegr;5-cyclopentadienyl ring coordinated to M; R′ or R″ each independently represents a group of an anionic nature a-bound to the metal M; B represents an unsaturated bivalent organic residue having from 1 to 30 carbon atoms, bound, respectively, to the ring of group A′ and to the —CH2— methylene group by means of carbon atoms. This complex, combined with a suitable cocatalyst, forms a catalyst with a high activity in the polymerization of olefins, producing polymers with a high molecular weight, especially in the case of the copolymerization of ethylene with a second &agr;-olefin.
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