发明授权
US06221969B1 Method for producing rubber-modified styrenic resin having high gloss and high impact strength
有权
生产具有高光泽度和高冲击强度的橡胶改性苯乙烯树脂的方法
- 专利标题: Method for producing rubber-modified styrenic resin having high gloss and high impact strength
- 专利标题(中): 生产具有高光泽度和高冲击强度的橡胶改性苯乙烯树脂的方法
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申请号: US09274278申请日: 1999-03-22
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公开(公告)号: US06221969B1公开(公告)日: 2001-04-24
- 发明人: Oh-jin Kwon , Yong-jun Kim , Hyung-sub Lee
- 申请人: Oh-jin Kwon , Yong-jun Kim , Hyung-sub Lee
- 优先权: KR98-9906 19980323
- 主分类号: C08F25500
- IPC分类号: C08F25500
摘要:
Disclosed is a method for producing a rubber-modified styrenic resin. The method includes the steps of (a) producing a rubber solution by dissolving a rubber polymer in a vinyl monomer; (b) producing a rubber composition by continuously supplying the above rubber solution in a first reactor to polymerize the rubber polymer with the vinyl monomer at a reaction temperature of 120°-145° C. to perform phase inversion of the rubber polymer, thereby producing the polymer of conversion ratio of 10-40 wt %, and realized through 50-99% of rubber particles having an average particle diameter of 0.1-0.5 &mgr;m, and 1-50% of rubber particles having an average particle diameter of 1-5 &mgr;m; (c) performing polymerization until conversion ratio reaches 70-90% by continuously supplying a reactant solution produced in the first reactor in a second, third and fourth reactor; and (d) separating the polymer containing a rubber component from unreacted monomer by continuously supplying a reaction solution resulting from the fourth reactor to a devolatilizer.
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