发明授权
- 专利标题: Processes for the production of polycarbonate
- 专利标题(中): 聚碳酸酯生产工艺
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申请号: US09068561申请日: 1999-05-05
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公开(公告)号: US06288203B1公开(公告)日: 2001-09-11
- 发明人: Akihiro Shishikura , Seiji Takahashi
- 申请人: Akihiro Shishikura , Seiji Takahashi
- 优先权: JP7/307324 19951127; JP7-321757 19951211
- 主分类号: C08G6400
- IPC分类号: C08G6400
摘要:
Processes for producing polycarbonate by solid phase polymerization which simplify the crytallization to be conducted prior to the solid phase polymerization to thereby permit further shortening in the treatment time. A process for producing polycarbonate is characterized in that an amorphous polycarbonate prepolymer prepared by transesterification of aromatic dihydroxy compound with a diester of carbonic acid is prepolymerized in a solid phase under an atmosphere containing gaseous swollen solvent while the prepolymer is kept in a fluid state. Another process for producing polycarbonate is characterized in that a mixture comprising an amorphous polycarbonate prepolymer prepared by transesterification of an aromatic dihydroxy compound with a diester of carbonic acid and a polycarbonate prepolymer which has undergone crystallization is prepolymerized in a solid phase under an atmosphere containing a gaseous swollen solvent.
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