发明授权
- 专利标题: Methods for cross-metathesis of terminal olefins
- 专利标题(中): 端烯烃的交错复分解方法
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申请号: US09491800申请日: 2000-01-26
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公开(公告)号: US06306988B1公开(公告)日: 2001-10-23
- 发明人: Robert H. Grubbs , Daniel J. O'Leary , Helen E. Blackwell
- 申请人: Robert H. Grubbs , Daniel J. O'Leary , Helen E. Blackwell
- 主分类号: C08F426
- IPC分类号: C08F426
摘要:
A method for the cross-metathesis of terminal olefins is disclosed. The method describes making disubstituted internal olefin products by contacting a first terminal olefin with another first terminal olefin to form a dimer and then contacting the dimer with a second terminal olefin in the presence of a catalyst having the formula where M may be Os or Ru, R and R1 may be the same or different and may be hydrogen or a substitutent group selected from C1-C20 alkyl, C2-C20 alkenyl,C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl, and C1-C20 alkylsulfinyl. X and X1 may be the same or different and may be any anionic ligand. L and L1 may be the same or different and may be any neutral electron donor.
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