发明授权
US06310259B1 Method for producing 6,10 and 6,9-dimethyl-5,10-undecadienyl-2-ones
失效
制备6,10和6,9-二甲基-5,10-十一二烯基-2-酮的方法
- 专利标题: Method for producing 6,10 and 6,9-dimethyl-5,10-undecadienyl-2-ones
- 专利标题(中): 制备6,10和6,9-二甲基-5,10-十一二烯基-2-酮的方法
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申请号: US09446734申请日: 2000-03-23
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公开(公告)号: US06310259B1公开(公告)日: 2001-10-30
- 发明人: Wilhelm Keim , Armin Kraus , Rainer Hahn , Klaus Huthmacher
- 申请人: Wilhelm Keim , Armin Kraus , Rainer Hahn , Klaus Huthmacher
- 优先权: DE19730546 19970717
- 主分类号: C07C4500
- IPC分类号: C07C4500
摘要:
The present application refers to a process for preparing 6,10- and 6,9-dimethyl-5,10-undecadienyl-2-ones by telomerizing isoprene with alkyl acetoacetates in the presence of a catalyst system containing a transition metal compound catalyst and a phosphorus- or arsenic-containing compound cocatalyst, wherein the process is performed in the presence of a protic additive of the general formula in which: R1, R2, R3 represent an alkyl group with 1 to 9 carbon atoms, branched or unbranched, a cycloalkyl group with 6 to 8 carbon atoms, an aryl group, in particular phenyl, or an arylalkyl group, X(−) represents an inorganic or organic anion, y is 1 or 2, and the &bgr;-ketoester so obtained is saponified and decarboxylated in a manner known per se.