The invention provides a process for producing solid electrolyte capacitors by forming a dielectric oxide film and a first cathode layer of solid conductive substance over the surface of an anode body of valve metal, and forming a second cathode layer of conductive high polymer on the first cathode layer by electrolytic oxidative polymerization. The second cathode layer is formed by immersing in the electrolyte the anode body formed over the surface thereof with the oxide film and the first cathode layer, feeding a positive voltage with an external electrode piece in contact with the first cathode layer in the electrolyte, and shifting the feeding point at a predetermined time interval.