发明授权
US06319875B1 Initiation system comprising a silylated initiator for anionic (co)polymerization of (meth)acrylic monomer(s) and process using same
失效
包括用于(甲基)丙烯酸单体的阴离子(共)聚合的甲硅烷基化引发剂的起始体系和使用它们的方法
- 专利标题: Initiation system comprising a silylated initiator for anionic (co)polymerization of (meth)acrylic monomer(s) and process using same
- 专利标题(中): 包括用于(甲基)丙烯酸单体的阴离子(共)聚合的甲硅烷基化引发剂的起始体系和使用它们的方法
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申请号: US09058481申请日: 1998-04-10
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公开(公告)号: US06319875B1公开(公告)日: 2001-11-20
- 发明人: Christophe Navarro , Axel H. E. Müller , Andreas R. Maurer , Robert Jerome , Thomas Zundel
- 申请人: Christophe Navarro , Axel H. E. Müller , Andreas R. Maurer , Robert Jerome , Thomas Zundel
- 优先权: FR9704468 19970410
- 主分类号: B01J3112
- IPC分类号: B01J3112
摘要:
The initiation system comprises (1) at least one silylated initiator and (2) at least one alkaline metal alcoholate as ligand. The silylated initiator may be monofunctional and selected in particular from among the compounds of Formula (I) or difunctional and selected in particular from among the compounds of Formula (II): wherein R1, R2, R3 each independently represent a C1-C8alkyl radical, linear or branched; R4 is a linear or branched C1-C8alkylene radical; M is an alkaline metal or alkaline earth metal (valence q of 1 or 2); R5 and R6 each independently represent an alkyl radical, linear or branched, at C1-C8; R7, R8 each independently represent a C1-C8alkylene radical, linear or branched; M′ is an alkaline metal. Application is to the preparation of (meth)acrylic (co)polymers.
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