An ink jet nozzle plate is provided comprising an outer surface having a self-assembled monolayer thereon comprising a mixture of at least one hydrophobic compound and at least one ionic compound, which monolayer renders the outer surface non-wetting with respect to aqueous ink solutions. In accordance with preferred embodiments, the self-assembled monolayers comprises a mixture of hydrophobic alkyl thiols and charged alkyl thiols. An advantage of coatings in accordance with the invention is that they provide improved non-wetting characteristics after contact with ink.