发明授权
- 专利标题: Method for producing butyrolactones
- 专利标题(中): 丁内酯的制备方法
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申请号: US09700426申请日: 2000-11-15
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公开(公告)号: US06346629B1公开(公告)日: 2002-02-12
- 发明人: Melanie Brunner , Ralf-Thomas Rahn , Udo Rheude , Jochem Henkelmann
- 申请人: Melanie Brunner , Ralf-Thomas Rahn , Udo Rheude , Jochem Henkelmann
- 优先权: DE19824534 19980603
- 主分类号: C07D30702
- IPC分类号: C07D30702
摘要:
Process for producing butyrolactones of the general formula I where R1 and R2 are each hydrogen, alkyl, hydroxyalkyl, substituted or unsubstituted aryl or substituted or unsubstituted trialkylsilyl, by reacting alkynes of the general formula II where R1 and R2 are each as defined above, with carbon monoxide and water in the presence of a rhodium catalyst under pressures from 20 to 300 bar and hydrogenating the unhydrogenated 2(5H)-furanone intermediates comprises a) reacting the carbonylation reaction mixture with hydrogen at from 150 to 250° C. and from 100 to 300 bar, b) removing the precipitated catalyst and returning it into the carbonylation reaction, and c) subjecting the catalyst-free reaction mixture to a distillation to recover the butyrolactone.
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