发明授权
- 专利标题: Method for producing 1,4-butanediol
- 专利标题(中): 生产1,4-丁二醇的方法
-
申请号: US09673134申请日: 2000-10-11
-
公开(公告)号: US06350924B1公开(公告)日: 2002-02-26
- 发明人: Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
- 申请人: Rolf Fischer , Gerd Kaibel , Rolf Pinkos , Ralf-Thomas Rahn
- 优先权: DE19818248 19980423
- 主分类号: C07C2700
- IPC分类号: C07C2700
摘要:
A process for preparing 1,4-butanediol and, if desired, &ggr;-butyrolactone and THF by oxidizing butane or benzene to form a product stream including maleic anhydride, absorbing maleic anhydride from the product stream with a high-boiling inert solvent in an absorption stage to give a liquid absorption product, esterifying the liquid absorption product with a C1-C5 esterifying alcohol in an esterification stage to form an esterification product comprising the corresponding diester and high-boiling inert solvent, then hydrogenating the esterification product to give a hydrogenation product which comprises the products of value, 1,4-butanediol and, if desired, &ggr;-butyrolactone and tetrahydrofuran and the esterifying alcohol and which is separated by distillation into the products of value and the esterifying alcohol, and recycling the esterifying alcohol to the esterification zone, which comprises separating the esterification product into the diester and the inert solvent by distillation under reduced pressure prior to the hydrogenation, recycling the inert solvent to the absorption stage, and hydrogenating the diester in the liquid phase over a fixed-bed catalyst.
信息查询