发明授权
US06391992B1 Sulfonate-terminated oligomers of vinyl esters and their vinyl alcohol oligomer derivatives
有权
乙烯基酯的磺酸酯封端的低聚物及其乙烯醇低聚物衍生物
- 专利标题: Sulfonate-terminated oligomers of vinyl esters and their vinyl alcohol oligomer derivatives
- 专利标题(中): 乙烯基酯的磺酸酯封端的低聚物及其乙烯醇低聚物衍生物
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申请号: US09157231申请日: 1998-09-18
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公开(公告)号: US06391992B1公开(公告)日: 2002-05-21
- 发明人: Robert Krantz Pinschmidt, Jr. , Khalil Yacoub
- 申请人: Robert Krantz Pinschmidt, Jr. , Khalil Yacoub
- 主分类号: C08F13004
- IPC分类号: C08F13004
摘要:
Oligomers of vinyl esters, preferably of vinyl acetate, are provided in which the molecules contain a single terminal sulfonate group, thereby making these products useful as surface-active agents. These oligomers can be converted by hydrolysis to sulfonate-terminated vinyl alcohol oligomer which is also a surface-active agent. The number average molecular weight of the vinyl ester oligomer is not over 17,000 and not over 7,500 for the vinyl alcohol oligomer. These products are made by polymerizing the vinyl ester in the presence of a bisulfite chain transfer agent in water, preferably with a cosolvent such as methanol. The vinyl ester is delay fed to the polymerization, molecular weight is controlled with the bisulfite, and the system is maintained in a virtual single phase with any organic phase present swollen with water or water and cosolvent.