发明授权
- 专利标题: Elastomeric copolymers of ethylene with &agr;-olefins and process for their preparation
- 专利标题(中): 乙烯与α-烯烃的弹性共聚物及其制备方法
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申请号: US09694160申请日: 2000-10-24
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公开(公告)号: US06403737B1公开(公告)日: 2002-06-11
- 发明人: Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
- 申请人: Maurizio Galimberti , Luigi Resconi , Enrico Albizzati
- 优先权: ITMI93A0943 19930511
- 主分类号: C08F442
- IPC分类号: C08F442
摘要:
A process for the preparation of amorphous copolymers of ethylene with &agr;-olefins and optionally minor amounts of polyenes are disclosed, which have the following characteristics: (A) the % by mole content of &agr;-olefin in the copolymer (%&agr;) and the ratio between the molar amount of &agr;-olefin diads and the molar content of &agr;-olefin in the copolymer (&agr;&agr;/&agr;) satisfy the following relationship: (%&agr;)−250 (&agr;&agr;/&agr;)≧10 (B) less than 2% of the CH2 groups in the polymeric chain are in sequences (CH2)n, wherein n is an even number. These copolymers are obtained by operating in the presence of particular metallocene-based catalysts having two fluorenyl groups joined together through a bridging group.
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