发明授权
US06403762B1 Solid state polymerization process for poly(trimethylene terephthalate) utilizing a combined crystallization/preheating step 失效
使用组合结晶/预热步骤的聚(对苯二甲酸丙二醇酯)的固态聚合方法

  • 专利标题: Solid state polymerization process for poly(trimethylene terephthalate) utilizing a combined crystallization/preheating step
  • 专利标题(中): 使用组合结晶/预热步骤的聚(对苯二甲酸丙二醇酯)的固态聚合方法
  • 申请号: US09891909
    申请日: 2001-06-26
  • 公开(公告)号: US06403762B1
    公开(公告)日: 2002-06-11
  • 发明人: Ben Duh
  • 申请人: Ben Duh
  • 主分类号: C08F600
  • IPC分类号: C08F600
Solid state polymerization process for poly(trimethylene terephthalate) utilizing a combined crystallization/preheating step
摘要:
The present invention is an improvement upon the process for producing poly(trimethylene terephthalate) (PTT) wherein 1,3-propanediol (PDO), and optionally other diols, and an aromatic diacid or diester thereof, and optionally other diacids or diesters, are esterified or transesterified and the esterification or transesterification product is polycondensed to produce a prepolymer which is solid state polymerized to produce a polymer with a desired intrinsic viscosity (IV). The prior art process includes the SSP prereaction steps of crystallization, drying/annealing, and preheating. The improvement in the present invention comprises crystallizing and preheating the PTT polymer in one step, without a drying/annealing step in between. Thus, the prepolymer still has a substantial moisture content when it is first exposed to the SSP reaction temperature inside the crystallizer/preheater.
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