发明授权
US06403821B1 Catalyst composition and method for producing diaryl carbonates using nitrile as promoter 有权
催化剂组合物和使用腈作助催化剂生产碳酸二芳酯的方法

Catalyst composition and method for producing diaryl carbonates using nitrile as promoter
摘要:
Hydroxyaromatic compounds such as phenol are carbonylated with oxygen and carbon monoxide in the presence of a catalyst system comprising a Group VIIIB metal, preferably palladium; an alkali metal or alkaline earth metal halide, preferably sodium bromide; and a promoter compound which is at least one C2-8 aliphatic or C7-10 aromatic mono- or dinitrile, preferably acetonitrile or adiponitrile. The catalyst system also preferably contains a compound of a non-Group VIIIB metal, preferably lead.
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