Invention Grant
US06407264B2 Synthesis of alkylene carbonates using a catalyst system comprising metal halide and pyridine or pyridine derivative 失效
使用包含金属卤化物和吡啶或吡啶衍生物的催化剂体系合成碳酸亚烷基酯

Synthesis of alkylene carbonates using a catalyst system comprising metal halide and pyridine or pyridine derivative
Abstract:
The present invention relates to a method to prepare alkylene carbonate of the formula (1) wherein, R1 and R2 are each independently H; C1-C4 alkyl or phenyl group; which method characterized by reacting alkylene oxide with carbon dioxide in the presence of a catalyst system comprising a) metal halide [MXm] and b) pyridine or pyridine derivative [Py], wherein Py is selected from a group of pyridines; M is a metal atom selected from the group consisting of Zn, Fe, Mn, Pb and In; X is a halogen selected from the group consisting of Cl, Br and I; and m is 2 or 3.
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